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The nutrients have been removed from the white distilled vinegar during the distillation process, so it wouldn't be helpful for the health of your hair. The best type of ACV to use as a rinse is the kind with "mother" in it (bits and particles of the apple that look like, for lack of a better word, "slime" floating in the bottle). This represents concentrated nutrients. The very best brand I can recommend is Bragg's. You can order it either online (www.bragg.com) or purchase it from your local health food store.