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If u are getting a b-complex, it should have both + more like thiamine, riboflavin or b2, niacin, folate or folic acid, and pantothenic acid.
b6 or pyridoxine is required as an enzymatic cofactor for carbohydrate and amino acid metabolism. assists in synthesis of blood cells.
b12 or cobalamin assists with formation of blood and is required for a healthy nervous system. It is an enzymatic cofactor of homocysteine.
I believe NoMoreWeave is saying neither is "better" for the hair. They work in conjunction with the other B vitamins to promote a healthy, functioning system. If you buy a B-50 or B-100 complex pill you won't have to choose between B-6 or B-12 because you'll get both in a large dose along with the other B vitamins by simply taking the one B-complex pill. Biotin is the B vitamin most recommended for hair growth and you already have that covered now you can just get the B-complex.