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If you've detangled as well as you can you'll probably be fine. When I got a virgin relaxer (in a salon) last year the tangles weren't a big deal and I hadn't thought much about it beforehand besides putting my hair in big twists. For some reason the relaxer process combined with the stylist's routine tends to minimize the effect of tangling.
The general consensus is that lye relaxers are better for the hair but harder on the scalp and vice-versa for no-lye relaxers. I'm very pleased with my lye relaxer .