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I've read some members mention that they experience burning if they do a relaxer after working out. That may not happen to everyone, but it's something to consider.
I would say no to relaxing after a workout because the pores on your scalp are open which can/may/will lead to burning, even if you base in some cases. If you must relax after working out, sit under a hair dryer that's on cool setting for about 15 mins (cold/cool air is being blown) out). This will close your pores and dry up the sweat from your workout.