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even natural oils in hair can sizzle and fry your hair......Only thing that should be in your hair when flat ironing is a leave-in and a heat protector....Add your oils when your done.....
I think if it works for you it works for you.
Some oils have a high boiling point-- some you should never flat iron with them on your hair because they have a low boiling point.
I use a serum that has coconut oil in it before I flatiron, I have used one with Olive Oil too. No problem. It is only a problem if you use too much or on too high heat.
Don't go crazy with the heat unless your hair is covered in silicones to combat it.
So that stuff in your siggy is a heat protectant?
You're frying your hair. Don't do it.You can lightly apply your oil when you're done styling.